张伟雄

张伟雄，中山大学“百人计划”引进人才，副教授，硕士生导师。

2004.09—2009.06：中山大学，无机化学专业硕博连读，博士

2000.09—2004.06：中山大学，应用化学专业，学士

2012.08至今：中山大学化学与化学工程学院，副教授

2010.06—2012.08：日本东北大学，日本学术振兴会（JSPS）博士后

2009.07—2010.06：中山大学化学与化学工程学院，科研助理

本科生课程：《基础化学实验I（无机）》、《基础化学实验IV（综合）》、《无机化学》、《现代无机化学进展》、《综合化学实验》；

研究生课程：《单晶结构分析》

功能配位化学，介电/磁性配合物，着重于：1）限域体系的分子电/磁极化效应的研究，2）基于单分子/单链磁体的新型多功能材料的设计、合成与相关性质研究。Researcher ID: D-3365-2011

主持国家自然科学基金青年项目、科技部“国家重大科学仪器设备开发专项”、教育部博士点基金、广东省自然科学基金、中山大学百人计划启动基金及青年教师重点培育项目等。

入选广东省特支计划科技创新青年拔尖人才，广州市珠江科技新星，广东省千百十人才培养工程校级培养对象。

综述：

1) Zhang, W.-X.*; Liao, P.-Q.; Lin, R.-B.; Wei, Y.-S.; Zeng M.-H.*; Chen, X.-M.* Metal cluster-based functional porous coordination polymers Coord. Chem. Rev. 2015, 293-294, 263-278.

2) Zhang, W. X.*; Ishikawa, R.; Breedlove, B. K.; Yamashita, H.* Single-chain magnets: beyond the Glauber model RSC Adv. 2013, 3, 3772−3798.

部分近期论文：

1) Xu, W.-J.; He, C.-T.; Ji, C.-M.; Chen, S.-L.; Huang, Y.-K.; Lin, R.-B.; Luo, J.-H.; Zhang, W.-X.*; Chen, X.-M. Molecular dynamics of flexible polar cation in variable confined space: toward exceptional two-step nonlinear optical switches Adv. Mater. 2016, DOI:10.1002/adma.201600895

2) Du, Z.-Y.; Xu, T.-T.; Huang, B.; Su, Y.-J.; Xue, W.; He, C.-T.; Zhang, W.-X.*; Chen, X.-M. Switchable guest molecular dynamics in a Perovskite-like coordination polymer toward sensitive thermo-responsive dielectric materials Angew. Chem. Int. Ed. 2015, 54, 914. “

3) Zhang, W. X.*; Shiga, T.; Miyasaka, H.; Yamashita, H.* New approach for designing single-chain magnets: organization of chains via hydrogen bonding between nucleobases J. Am. Chem. Soc. 2012, 134, 6908−6911.

4) He, C.-T.; Liao, P.-Q.; Zhou, D.-D.; Wang, B.-Y.; Zhang, W.-X.*; Zhang, J.-P.*; Chen,X.-M. Visualizing the distinctly different crystal-to-crystal structural dynamism and sorption behavior of interpenetration-direction isomeric coordination networks Chem. Sci., 2014, 5, 4755-4762.

5) Du, Z.-Y.*; Sun, Y.-Z.; Chen, S.-L.; Huang, B.; Su, Y.-J.; Xu, T.-T.; Zhang, W.-X.*; Chen, X.-M. Insight into the molecular dynamics of guest cations confined in deformable azido coordination frameworks Chem. Commun. 2015, 51, 15641.

6) Du, Z.-Y.; Zhao, Y.-P.; Zhang, W. X.*; Zhou, H.-L.; He, C.-T.; Xue, W.; Wang, B.-Y.; Chen, X.-M. Above-room-temperature ferroelastic phase transition in a Perovskite-like cage compound [N(CH3)4][Cd(N3)3] Chem. Commun. 2014, 50, 1989–1991.

7) Du, Z.-Y.; Zhao, Y.-P.; He, C.-T.; Wang, B.-Y.; Xue, W.; Zhou, H.-L.; Bai, J.; Huang, B,; Zhang, W.-X.*; Chen, X.-M.* Structural transition in the Perovskite-like bimetallic azido coordination polymers: (NMe4)2[B'*B''(N3)6] (B' = Cr3+, Fe3+; B'' = Na+, K+) Cryst. Growth Des., 2014, 14, 3903–3909.

8) Xu, W.-J.; Chen, S.-L.; Hu, Z.-T.; Lin, R.-B.; Su, Y.-J.; Zhang, W.-X.*; Chen, X.-M.* The cation-dependent structural phase transition and dielectric response in a family of cyanobridged perovskite-like coordination polymers Dalton Trans. 2016, 45, 4224–4229.

9) Wang, B.-Y.; Xu, W.-J.; Xue, W.; Lin, R.-B.; Du, Z.-Y.; Zhou, D.-D.; Zhang, W.-X.*; Chen, X.-M. Restraining the motion of ligand for modulating the structural phase transition in two isomorphic polar coordination polymers Dalton Trans., 2014, 43, 9008-9011.

10) Li, F.; Lin, Y.-B.; Wei, Y.-S.; Liao, P.-Q.; Bai, J.; Xue, W.; Zhang, W.-X.*; Zhang, J.-P.*; Chen, X.-M. Metal-ion controlled solid-state reactivity and photoluminescence in two isomorphous coordination polymers Inorg. Chem. Front., 2014, 1, 172–177.

11) Bai J.; Zhou H.-L.; Liao P.-Q.; Zhang, W.-X.*; Chen X.-M. Structural diversity of coordination polymers controlled by the metal ion as the sole reaction variable CrystEngComm 2015, 17, 4462-4468.

12) Qi, X.-L.; Zhang, C.; Wang, B.-Y.; Xue, W.; He, C.-T.; Liu, S.-Y.; Zhang, W. X.*; Chen, X.-M.* Two new polar coordination polymers with diamond networks: interpenetration and thermal phase transition CrystEngComm 2013, 15, 9530−9536.

13) Wang, B. Y; He, C. T.; Huang, B.; Xu, W. J.; Xue, W.; Du, Z. Y.; Zhang, W. X.*; Chen, X. M. Thermal-induced reversible ferroelastic phase transition in a new bromethyl-substituted molecular rotor Sci. Chin. Chem. 2015, 58, 1137-1143.

14) Liao, P.-Q.; Zhang, W.-X.; Zhang. J.-P.; Chen, X.-M. Efficient purification of ethene by an ethane-trapping metal-organic framework Nat. Commun. 2015, 6, 8697.

15)Liao, P.-Q.; Zhu, A.-X.; Zhang, W.-X.; Zhang, J.-P.*; Chen, X.-M. Self-catalysed aerobic oxidization of organic linker in porous crystal for on-demand regulation of sorption behaviours Nature Commun. 2015, 6, 6350.

16) Zeng, M.-H.*; Yin, Z.; Tan Y.-X.; Zhang, W.-X.; He, Y.-P.; Kurmoo, M. Nanoporous Cobalt(II) MOF Exhibiting Four Magnetic Ground States and Changes in Gas Sorption upon Post-Synthetic Modification J. Am. Chem. Soc., 2014, 136, 4680–4688.