汤杰,法国居里大学(巴黎第六大学)博士,法国国家科研中心(CNRS)博士后。
现为华东师大化学系教授、博士生导师,药物化学研究所所长,上海市化学化工学会有机化学专业委员会委员;《有机化学》编委、《化学通报》第12届编委、《华东师范大学学报》编委。
汤杰,中国常用人名,比较著名的嗨有工艺美术师汤杰和演员汤杰。
人物经历
1996年回国工作。
研究方向
有机合成与有机合成方法学、金属有机化学、甾体药物化学。
主要贡献
汤杰他主持国家自然科学基金、上海市科委重点研究项目有多项。
主要论文及专利:
1. An efficient silica-grafted poly-(L)-leucine catalyst for asymmetric epoxidation of a, b-unsaturated ketone, J. Mol. Catal. A: Chemical, 2007
2. Palladium-Catalyzed Ring Enlargement of Aryl-Substituted Methylene- cyclopropanes to Cyclobutenes, J. Am. Chem. Soc., 2006, 128, 7430-7431.
3. Palladium-Catalyzed Cross-Coupling Reaction of 2-Iodo-4-(phenylchalcogenyl) -1-butenes, J. Org. Chem., 2005, 70, 10420-10425.
4. Enynylation of 2-Iodo-4- (phenylchalcogenyl) -1-butenes via Intramolecular Chelation: Approch to the Synthesis of Conjugated Dienynes or Trienynes, Org. Lett., 2005, 7(14), 3085.
5. Palladium-benzimidalium salt catalyst systems for Suzuki coupling: development of a practical and highly active palladium catalyst system for coupling of aromatic halides with arylboronic acids, Tetrahedron, 2005, 61, 9783-9790.
6. Asymmetric epoxidation of a,b-unsaturated ketones catalyzed by silica-grafted poly-(L)-leucine catalysts, Tetrahydron Lett., 2005, 46, 5665.
7. A Novel and Efficient Process for Preparation of 2,4-Diphenyl-4-methyl-1- pentene in Brönsted Acidic Ionic Liquid [Hmim]+BF4-, Chin. J. Chem., 2005, 23, 581.
8. Suzuki Coupling Reaction Catalyzed by Cyclopalladated Complexes of Tertiary Arylamines in Ionic Liquid, Chin. Chem. Lett., 2005, 16(9), 1173.
9. Oxidation of toluenes to benzoic acids by oxygen in non-acidic solvents, Tetrahedron, 2004, 60, 1225.
10. An unprecedented rhodium-catalysed self-conjugate reduction, cross-coupling tandem reaction of cinnamaldehydes with arylboronic acids, Chem. Commun., 2004, 1192-1193.
11. An efficient procedure for protection of carbonyls in Bronsted acidic ionic liquid [Hmim]BF4, Tetrahedron Lett., 2004, 45(25), 4963.
12. Immobilization of HX: [Hmim]X as Halogenating Agent, Recyclable Catalyst and Medium for Conversion of Alcohols to Alkyl Halides, Chin. J. Chem., 2004, 22, 619.
13. Homocoupling of Aryl Iodides Catalyzed by Cyclopalladated Complexes of Tertiary Arylamines, Chin. J. Chem., 2004, 22(5), 419.
14. Bronsted Acidic Ionic Liquid 1-Methylimidazolium Tetrafluoroborate: A Green Catalyst and Recyclable Medium for Esterification, Green Chemistry, 2003, 5, 38.
15. Rhodium-catalyzed Heck-type reaction of arylboronic acids with a,b-unsaturated esters: tuning b-hydrogen elimination vs. hydrolysis of alkylrhodium species, Chem. Commun., 2003, 2438.
16. Cross-coupling of arylboronic acids with terminal alkynes in air, Tetrahedron Lett., 2003, 44, 8709–8711.
17. Developing an ionic medium for ligandless-palladium-catalysed Suzuki and Heck couplings, J. Mol. Catalysis A: Chemical, 2003, 206, 193-198.
18. Synthesis, Biochemical Properties and Molecular Modelling Studies of Organometallic Specific Estrogen Receptor Modulators (SERMs), the Ferrocifens and Hydroxyferrocifens: Evidence for an Antiproliferative Effect of Hydroxyferrocifens on both Hormone-Dependent and Hormone-Independent Breast Cancer Cell Lines, Chem. Eur. J. 2003, 9, 5223-5236.
19. Heptadecafluorooctanesulfonic acid catalyzed reactions of methylenecyclopropanes on aromatic amines, sulfonamides and alcohols in supercritical carbon dioxide, Green Chem., 2003, 5, 85-88.
20. Crystal Structure of Chiral Acetato-bridged Binuclear Cyclopalladated Complex [Pd(μ-O2CMe)(S-C6H4CHMeNH2)]2, Chin. J. Chem., 2003, 21(8), 1039.
21. Heck reaction of iodoarenes with methyl acrylate catalyzed by cyclopalladated complexes of tertary arylamines immobilized in ionic liquid [Bmim]+BF4-, Chin. J. Chem., 2003, 21, 1111.
22. Synthesis of cyanobenzaldehydes (o-, m-, p-) by molecular oxygen oxidation methods, Chin. J. Chem., 2002, 20, 76.
23. Cyclopalladated complexes of tertiary arylamines catalyzing the Heck reaction in ionic liquid [Bmim]+BF4, J. Organomet. Chem., 2002, 651, 146.
24. Immobilization of Pd(II) catalysts for cyclopropanation of ionic liquid, Chin. J. Chem., 2002, 20, 114.
25. A novel ring-opening reaction of methylenecyclopropanes with aromatic amines catalyzed by Lewis acids, Tetrahedron Letters, 2002, 43, 8019-8024.
26. A New Convenient Method for the Synthesis of Formyl Ferrocene, Syn. Commun., 2000, 1657.