柯卓锋

柯卓锋，男，1980年10月出生于广东，是一位理学博士。他是中山大学“百人计划”引进的人才，同时也是材料科学与工程学院的教授和博士生导师。

2019 - 至今中山大学，材料科学与工程学院，教授/博导

2016－2018 中山大学，材料科学与工程学院，副教授/博导

2012－2016 中山大学，化学院，副教授/博导

2009－2012 日本京都大学，福井谦一FIFC研究员

2005－2009 中山大学/美国北德克萨斯大学，物理化学，联合培养博士

2002－2005 中山大学，高分子化学与物理，硕士

1998－2002 中山大学，化学系，本科

广东省自然科学杰出青年(2015)

广东特支计划百千万工程青年拔尖人才(2014)

福井谦一FIFC Fellow（2009-2012）

1. 可再生能源、可再生资源与材料

2. 可再生催化与合成新方法

3. 理论计算精准催化剂设计

1. Zhang, M., Zhang, M.-T., Hou, C., Ke, Zhuo-Feng*, Lu T.-B.* Homogeneous Electrocatalytic Water Oxidation at Neutral pH by a Robust Macrocyclic Nickel(II) Complex.Angew. Chem., Int. Ed. DOI: 10.1002/anie.201406983 (2014).

2. Hou, C., Jiang J., Zhang S., Wang G., Zhang Z., Ke, Zhuofeng*, Zhao C.* Hydrogenation of Carbon Dioxide Using Half-Sandwich Cobalt, Rhodium, and Iridium Complexes: DFT Study on the Mechanism and Metal Effect.ACS Catal. 4, 2990–2997 (2014).

3. Zhou, Y.G., Zhang, X.P., Liang H.Y., Cao Z.K., Zhao X.Y., He Y.W., Wang S.L., Pang J.Y., Zhou Z.Y., Ke, Zhuofeng*, Qiu L.Q.* Enantioselective Synthesis of Axially Chiral Biaryl Monophosphine Oxides via Direct Asymmetric Suzuki Coupling and DFT Investigations of the Enantioselectivity.ACS Catal. 4, 1390–1397 (2014).

4. Petrovaa, G.P., Ke, Zhuofeng, Park S., Sugiyama H., Morokum K.* The origin of enantioselectivity for intramolecular Friedel–Crafts reaction catalyzed by supramolecular Cu/DNA catalyst complex.Chem. Phys. Lett. 600, 87-95 (2014).

5. Zhang, X., Ke, Zhuofeng, DeYonker N. J., Xu, H., Li Z.-F., Xu X., Zhang X., Su C.-Y., Phillips D. L., Zhao C.* Mechanism and Enantioselectivity of Dirhodium-Catalyzed Intramolecular C–H Amination of Sulfamate.J. Org. Chem. 78 (24), 12460–12468 (2013).

6. Liu, Y., Ma, L., Chen, W.-H.*, Park, H., Ke, Zhuofeng*, Wang, B*. Binding Mechanism and Synergetic Effects of Xanthone Derivatives as Noncompetitive α-Glucosidase Inhibitors: A Theoretical and Experimental Study.J. Phys. Chem. B 117 (43), 13464 -13471 (2013).

7. Ye, R.-R., Ke, Zhuo-Feng, Tan, C.-P., He, L., Ji, L.-N. & Mao, Z.-W. Histone-Deacetylase-Targeted Fluorescent Ruthenium(II) Polypyridyl Complexes as Potent Anticancer Agents.Chem. Eur. J. 19 (31), 10160 – 10169 (2013).

8. Xu, H. Y., Zhang, X. T., Ke, Zhuofeng, Li, Z. F., Xu, X. Y., Su, C. Y., Phillips, D. L. & Zhao, C. Y. Density functional theory study of the mechanism of zinc carbenoid promoted cyclopropanation of allenamides.Rsc Advances 3, 17131-17142 (2013).

9. Ke, Zhuofeng, Abe, S., Ueno, T., & Morokuma, Keiji. Catalytic Mechanism in Artificial Metalloenzyme: QM/MM Study of Phenylacetylene Polymerization by Rhodium Complex Encapsulated in apo-Ferritin.J. Am. Chem. Soc. 134 (37), 15418–15429 (2012).

10. Ke, Zhuofeng, Abe, S., Ueno, T., & Morokuma, Keiji. Rh-catalyzed Polymerization of Phenylacetylene: Theoretical Studies of the Reaction Mechanism, Regioselectivity and Stereoregularity.J. Am. Chem. Soc. 133 (20), 7926-7941 (2011). (JACS beta Select issue 13)

11. Liu, Y., Ke, Zhuofeng, Liu, Shuwen, Chen, Wen-Hua, Jiang, Shibo; Jiang, Zhi-Hong. "An Amphiphilic Conjugate Approach toward the Design and Synthesis of Betulinic Acid-Polyphenol Conjugates as Inhibitors of the HIV-1 gp41 Fusion Core Formation ".ChemMedChem 6 (9), 1654- 1664 (2011).

12. Gao, H., Ke, Zhuofeng, DeYonker N.J., Wang J., Xu H., Mao Z.-W., Phillips, D.L., Zhao C., Dinuclear Zn(II) Complex Catalyzed Phosphodiester Cleavage Proceeds via a Concerted Mechanism: A Density Functional Theory Study.J. Am. Chem. Soc. 133 (9), 2904–2915 (2011).

13. Ke, Zhuofeng & Cundari, T.R., Palladium-Catalyzed C-H Activation/C-N Bond Formation Reactions: DFT Study of Reaction Mechanisms and Reactive Intermediates.Organometallics 29 (4), 821-834 (2010). (Top10 Most Accessed Articles of Organometallics in 2010)

14. Lee, J.P., Ke, Zhuofeng, Ramirez, M.A., Gunnoe, T.B., Cundari, T.R., Boyle, P.D., & Petersen, J.L., Six-, Five-, and Four-Coordinate Ruthenium(II) Hydride Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis, Characterization, Fundamental Reactivity, and Catalytic Hydrogenation of Olefins, Aldehydes, and Ketones.Organometallics 28 (6), 1758-1775 (2009).

15. Guo, Z., Xue, J.D., Ke, Zhuofeng, Phillips, D.L., & Zhao, C.Y., Influence of Water Hydrogen Bonding on the Reactions of Arylnitrenium Ions With Guanosine: Hydrogen-Bonding Effects Can Favor Reaction at the C8 Site.J. Phys. Chem. B 113 (18), 6528-6532 (2009).

16. Foley, N.A., Lee, J.P., Ke, Zhuofeng, Gunnoe, T.B., & Cundari, T.R., Ru(II) Catalysts Supported by Hydridotris(pyrazolyl)borate for the Hydroarylation of Olefins: Reaction Scope, Mechanistic Studies, and Guides for the Development of Improved Catalysts.Acc. Chem. Res. 42 (5), 585-597 (2009).

17. Liu, Y., Ke, Zhuofeng, Cui, J.F., Chen, W.H., Ma, L., & Wang, B., Synthesis, inhibitory activities, and QSAR study of xanthone derivatives as alpha-glucosidase inhibitors.Bioorg. Med. Chem. 16 (15), 7185-7192 (2008).

18. Guo, Z., Ke, Zhuofeng, Phillips, D.L., & Zhao, C.Y., Intrinsic reaction coordinate analysis of the activation of CH4 by molybdenum atoms: A density functional theory study of the crossing seams of the potential energy surfaces.Organometallics 27 (2), 181-188 (2008).

19. Foley, N.A., Ke, Zhuofeng, Gunnoe, T.B., Cundari, T.R., & Petersen, J.L., Aromatic C-H activation and catalytic hydrophenylation of ethylene by TpRu{P(OCH2)(3)CEt}(NCMe)Ph.Organometallics 27 (13), 3007-3017 (2008).

20. Lin, X.F., Zhao, C.Y., Che, C.M., Ke, Zhuofeng, & Phillips, D.L., A DFT study on the mechanism of Rh-2(II,II)-catalyzed intramolecular amidation of carbamates.Chem. Asian J. 2 (9), 1101-1108 (2007).

21. Ke, Zhuofeng, Zhou, Y.B., Gao, H., Zhao, C.Y., & Phillips, D.L., On the mechanism and stereochemistry of chiral lithium-carbenoid-promoted cyclopropanation reactions.Chem. Eur. J. 13 (23), 6724-6731 (2007).

22. Ke, Zhuofeng, Zhao, C.Y., & Phillips, D.L., Methylene transfer or carbometalation? A theoretical study to determine the mechanism of lithium carbenoid-promoted cyclopropanation reactions in aggregation and solvation states.J. Org. Chem. 72 (3), 848-860 (2007).

23. Gao, H.Y., Ke, Zhuofeng, Pei, L.X., Song, K.M., & Wu, Q., Drastic ligand electronic effect on anilido-imino nickel catalysts toward ethylene polymerization.Polymer 48 (25), 7249-7254 (2007).

24. Fang, R., Ke, Zhuofeng, Shen, Y., Zhao, C.Y., & Phillips, D.L., Concurrent cyclopropanation by carbenes and carbanions? A density functional theory study on the reaction pathways.J. Org. Chem. 72 (14), 5139-5145 (2007).

25. Zhou, Y.B., Ke, Zhuofeng, & Zhao, C.Y., A theoretical study on the mechanism of ruthenium(II)-catalyzed reaction of organic azide with alkyne.Acta Chim. Sin. 64 (20), 2071-2078 (2006).

26. Zhang, J.K., Ke, Zhuofeng, Bao, F., Long, J.M., Gao, H.Y., Zhu, F.M., & Wu, Q., Ethylene polymerization and oligomerization catalyzed by bulky beta-diketiminato Ni(II) and beta-diimine Ni(II) complexes/methylaluminoxane systems.J. Mol. Catal. A: Chem 249 (1-2), 31-39 (2006).

27. Ye, G.D., Ke, Zhuofeng, Yan, J.W., Zhao, T.Y., Zeng, Z.H., & Chen, Y.L., Low VOC bifunctional photoinitiator based on alpha-hydroxyalkylphenone structure.Polymer 47 (13), 4603-4612 (2006).

28. Li, Z.H., Ke, Zhuofeng, Zhao, C.Y., Geng, Z.Y., Wang, Y.C., & Phillips, D.L., A density functional theory study of aluminum carbenoid (CH3)(2)AlCH2X (X = Cl, Br, I) promoted cyclopropanation reactions compared to IMCH2I (M = Li, Sm, Zn) carbenoids.Organometallics 25 (15), 3735-3742 (2006).

29. Zhang, J.K., Gao, H.Y., Ke, Zhuofeng, Bao, F., Zhu, F.M., & Wu, Q., Investigation of 1-hexene isomerization and oligomerization catalyzed with beta-diketiminato Ni(II) bromide complexes/methylaluminoxane system. 231 (1-2), 27-34 (2005).