李全新(Male),男,1964年1月5日出生于中国安徽安庆,博士,中国科学技术大学教授、博士生导师。在材料和环境科学、激光化学领域有着深入研究,尤其在自由基发射功能材料及其在环境化学中的应用研究方面取得显著成就。
人物经历
1964年1月5日出生于中国安徽安庆。
1980.9~1984.7 安徽大学物理系,固体物理,本科。
1987.9~1990.12 中国科技大学,化学物理,硕士。
1991.2~1993.7 中国科技大学,化学物理,博士。
1993.9~1995.8 中国科技大学 讲师。
1996.10~1998.7 中国科技大学,副教授。
1998.8~2002.7 日本东京大学化学系统工学系 副教授。
2002.8–至今 中国科学技术大学化学物理系, 教授/博导。
科研成果
在国内外主要学术刊物上已发表论文90余篇,申请两项国际发明专利(Patent No:JPA2004160374,Patent No:JP2005009924),申请6项国内发明专利(公开号:101177239A,200810123420.3),获得国家科技进步奖二等奖(2005)一次,首创用合成多孔材料产生具有极强氧化性的氧负离子自由基方法。近年,在国家重点基础研究发展计划(973计划)课题“生物油重整制氢反应机理和基本规律研究”的资助下,开展了以“生物质能源和新型功能材料的基础与应用研究”为主要方向的课题研究工作。主要科研成果包括:(1)发明了适合生物油重整制氢的Ni-Cu-Ce-Mg-Al催化剂和Ni/Fe/Co/K/C12A7催化剂,初步研究了电化学催化条件下(催化剂中通过电流)生物油水蒸汽催化重整制氢新工艺;(2)研究和筛选了一系列生物油水蒸汽重整制氢催化剂,包括Ni-Al催化剂、C12A7-Mg催化剂、Ni-Cu-Zn-Al催化剂、Ni-Cu-Ce-Mg-Al催化剂、N—Fe-Co-K-C12A7催化剂等,初步研究了催化剂结构与生物油转化效率间的关系;(3)通过与日本的富山大学椿范立教授合作,利用新研制的低温低压甲醇合成方法,实现了在低温低压条件下高效合成生物质基甲醇和混合醇,研究了生物质基合成气合成汽油和柴油;(4)成功合成了H-和OH-储存-发射材料;实现了苯直接羟基化合成苯酚。目前正在承担国家973计划"生物质转化为高品位燃料的基础问题研究"和国家863计划专题课题"可再生的生物质资源制氢技术研究和开发"以及国家自然科学基金"新型氟/氯负离子储存-发射功能材料及其在半导体蚀刻中应用基础研究"。
李全新于2005年荣获国家科技进步二等奖。
研究领域
代表论文
(1) “High efficient production of hydrogen from crude bio-oil via an integrative process between gasification and current-enhanced catalytic steam reforming” - Int. J. Hydrogen Energy - 2010 - 35,518-532
(2) “Hydrogen production by low-temperature reforming of organic compounds in bio-oil over a CNT-promoting Ni catalyst” - Int. J. Hydrogen Energy - 2009 - 34, 9095–9107
(3) “Effects of current upon hydrogen production from electrochemical catalytic reforming of acetic acid” - Int. J. Hydrogen Energy, - 2009 - 34, 1760-1770.
(4) Surface Modification of Medical Poly(vinyl chloride) with O- Water - Journal of Applied Polymer Science - 2008 - DOI 10.1002/app
(5) Effects of current upon low-temperature electrochemical catalytic reforming of acetic acid - International Journal of Hydrogen Energy - 2008 - 34(4),1760-1770,
(6) Surface modification of polystyrene with atomic oxygen radical anions-dissolved solution - Applied Surface Science - 2008 - 254, 4191–4200
(7) “High efficient production of hydrogen from bio-oil using low-temperature electrochemical catalytic reforming approach over NiCuZn-Al2O3 catalyst - Catalysis Letters, - 2008 - DOI:0.1007/s10562
(8) Characteristics and Mechanism of Atomic Fluorine Anions Emission from Nanoporous Crystal [Ca24Al28O64]4+•(F–)3.36(O2–)0.32 Surface - The Journal of Physical Chemistry C - 2008 - 10.1021/jp805681q
(9) “Atomic fluorine anion storage-emission materialC12A7-F- and etching of Si and SiO2 by atomic fluorine anions” - Chemistry of Materials, (2008) - 2008 - 20(10),3473~3479,
(10) Electrochemical catalytic reforming of oxygenated-organic compounds over NiO/Al2O3 catalyst: a high efficient low-temperature reforming method for production of hydrogen from bio-oil - Chemical Communications - 2008 - DOI: 10.1039/b810851j
(11) - Letters in Applied Microbiology - 2007 - 45 (2007) 200–205
(12) Hydrogen Production by Steam Reforming of Ethanol on Potassium-Doped 12CaO-7Al2O3 Catalyst, - Catal. Lett. - 2007 - 119, 29
(13) Characteristics of Bio-Oil-Syngas and Its Utilization in Fischer-Tropsch Synthesis,Energy & Fuels, 2007, 21, 2421-2432 - Energy & Fuels - 2007 - 21, 2421-24
(14) Production of hydrogen from catalytic steam reforming of bio-oil using C12A7-O_-based catalysts, - Applied Catalysis A: General, - 2007 - 320, 24-34
(15) Substitution of H-for O-and H- emissions of 12CaO 7Al2O3l - APPLIED PHYSICS LETTERS - 2005 - 86,114101
(16) High-intensity atomic oxygen radical anion emission from12CaO· 7Al2O3 crystal surface - Surface Science, . - 2003 - in press
(17) Desorption of C2- anion from Au-C-deposited Y2O3 stabilized ZrO2 Surface - J. Phys. Chem. B, - 2003 - in press
(18) Absolute emission current density of O- from C12A7 crystal - Applied Phys. Letts - 2002 - 80, 4259-4261
(19) Reproducibility of O- Negative Ion Emission from C12A7 Crystal Surface - Jap. J. Applied Phys., - 2002 - 41, L238-240
(20) Theoretical investigation on the N + SF2 NS+ reaction involving resonance-enhanced multiphoton ioniz - J. Chem. Phys., - 2002 - 117,6519-6523
(21) “Study on the Resonance Enhanced Multiophoton Ionization Studies of 4s and C atates of SF2 Radical - J. Electron Spectr. And Related Phenomena, - 2002 - 108, 135
(22) Experimetal studies and ab initio calculation on the characteristics of C state of SF2 radical - Surf. Rev. Lett.,. - 2002 - 9, 69-75
(23) C. F. Song, J. Q. Sun, S. B. Qiu, L. X. Yuan, J.Tu, Y. Torimoto, M. Sadakata, Q. X. Li,“Atomic Fluorine Anion Storage EmissionMaterial C-12A7-Fand Etching of Si and SiO2 by Atomic Fluorine Anions”. Chem. Mater.,2008, 20, 3473–3479.
(24) L. X. Yuan, Y. Q. Chen, C. F. Song, T. Q. Ye, Q. X. Guo, Q.S. Zhu, Y. Torimoto and Q. X. Li, “Electrochemical catalytic reforming of oxyge-nated-organic compounds: a highly efficient method for production of hydrogen from bio-oil”, Chemical Communication, 2008, 5215-5217.
(25) Tao Kan, Jiaxing Xiong, Xinglong Li, Tongqi Ye, Lixia Yuan,Youshifumi Torimoto, Mitsuo Yamamoto, Quanxin Li*,High efficient production of hydrogen from crude bio-oil via an integrative process between gasification and current enhanced catalytic steam reforming,Int. J. Hydrogen Energy, 35(2), 518-532, 2010
(26) Yong Xu, Tong-qi Ye, Song-bai Qiu, Shen Ning, Fei-yan Gong, Yong Liu, Quanxin Li*,“High efficient conversion of CO2-rich bio-syngas to CO-rich bio-syngas using biomass char: a useful approach for production of bio-methanol from bio-oil”, Bioresource Technology,102(10), 6239–6245,2011
(27) Feiyan Gong, Zhi Yang, Chenggui Hong, Weiwei Huang, Shen Ning, Zhaoxia Zhang, Yong Xu and Quanxin Li*, “ Selective conversion of bio-oil to light olefins: Controlling catalytic cracking for maximum olefins” Bioresource Technology, 102(19), 92-47–9254, 2011
(28) Weiwei Huang, Feiyan Gong, Minghui Fan, Qi Zhai, Chenggui Hong, and Quanxin Li*,Production of light olefins by catalytic conversion of lig-nocellulosic biomass with HZSM-5zeolite impregnated with 6 wt.% lanthanum,Bioresource Technology,121, 248–255,2012
(29) Bi, P.Y., Yuan, Y.N., Fan, M.H., Jiang, P.W., Zhai Q., Li, Q.X.,. Production of aromatics through current-enhanced catalytic conversion of bi-o-oil tar. Bioresource Technology, 2013, 136: 222–229.
(30) Fan, M.H., Jiang, P.W., Bi, P.Y., Deng, S.M., Zhai, Q., Yan, L.F., Wang, T.J., Li, Q.X.,Directional synthesis of ethylbenzene through catalyti-c transformationof lignin.Bioresource Technology,2013,143: 59–67。